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Reactions of thioesters of trivalent phosphorus acids with complex alkali-metal hydrides

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Thioesters of phosphinous, phosphonous, and diaminophosphorous acids react with lithium aluminum hydride to form the corresponding primary and secondary phosphines or diamides of hypophosphorous acid.

  2. 2.

    The use of crown ethers as phase-transfer catalysts in reduction reactions of thioesters of pIII acids makes it possible to increase the rate of the process and raise the yield of the final products.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    O. G. Sinyashin, I. Yu. Gorshunov, N. V. Ivasyuk, É. S. Batyeva & A. N. Pudovik

Authors
  1. O. G. Sinyashin
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  2. I. Yu. Gorshunov
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  3. N. V. Ivasyuk
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  4. É. S. Batyeva
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  5. A. N. Pudovik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1394–1397, June, 1986.

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Sinyashin, O.G., Gorshunov, I.Y., Ivasyuk, N.V. et al. Reactions of thioesters of trivalent phosphorus acids with complex alkali-metal hydrides. Russ Chem Bull 35, 1267–1269 (1986). https://doi.org/10.1007/BF00956612

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  • DOI: https://doi.org/10.1007/BF00956612

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