Conclusions
In the interaction of salts of 1,1,1,3,5,5,5-heptanitro- or 1,5-difluoro-1,1,3,5,5-pentanitropentanes with nitrating systems based on HNO3, 1,1,1,3,3,5,5,5-octanitro- or 1,5-difluoro-1,1,3,3,5,5-hexanitropentanes, 1,1,1,5,5,5-hexanitro- or 1,5-difluoro-1,1,5,5-tetranitropentan-3-ones, the O-bis-(2,2,2-trinitroethyl)nitromethyl ether of bis(2′,2′,2′-trinitroethyl)carboxime or the O-bis(2-fluoro-2,2-dinitroethyl)nitromethyl ether of bis(2′-fluoro-2′,2′-dinitroethyl)carboxime are formed. The ratio of the reaction products depends on the composition of the nitrating system. The data obtained permit us to consider that the nitrating reagent is a nonionized form of HONO2 or AcONO2.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1357–1361, June 1986.
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Eremenko, L.T., Oreshko, G.V. & Fadeev, M.A. Peculiarities of the nitration of secondary polynitroalkanes. Russ Chem Bull 35, 1232–1235 (1986). https://doi.org/10.1007/BF00956604
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DOI: https://doi.org/10.1007/BF00956604