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Stable perfluorinated cyclic carbanions and their NMR spectra

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Perfluoro-1-alkylcyclocarbanions were synthesized from perfluoro-1-ethylcyclobutene, perfluoro-1-methylcyclopentene, perfluoro-1-ethylcyclohexene and CsF in DMF and were identified by19F and13C NMR spectra. Perfluoro-1-alkylcyclocarbanions add chlorine to form 1-chloro-1-perfluoroalkylcycloalkanes.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. F. Snegirev, N. I. Delyagina & V. I. Bakhmutov

Authors
  1. V. F. Snegirev
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  2. N. I. Delyagina
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  3. V. I. Bakhmutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1325–1331, June, 1986.

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Snegirev, V.F., Delyagina, N.I. & Bakhmutov, V.I. Stable perfluorinated cyclic carbanions and their NMR spectra. Russ Chem Bull 35, 1201–1206 (1986). https://doi.org/10.1007/BF00956598

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  • DOI: https://doi.org/10.1007/BF00956598

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