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Polyfluorinated anions and cations — Intermediates in reactions of fluorine-containing vinyl ethers

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The existence of polyfluorinated cations as intermediates in reactions of polyfluorine-containing vinyl ethers with electrophilic reagents has been proved.

  2. 2.

    13C and19F NMR parameters were obtained of cations and anions formed from 1-methoxyperfluoro-2-methyl-1-propene and 3-methoxyperfluoro-2-methyl-2-pentene.

  3. 3.

    Perfluorinated acylium cation was obtained from the first time and was identified by13C and19F NMR methods.

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Authors and Affiliations

  1. N. A. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. F. Snegirev, M. V. Galakhov, V. A. Petrov, K. N. Makarov & V. I. Bakhmutov

Authors
  1. V. F. Snegirev
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  2. M. V. Galakhov
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  3. V. A. Petrov
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  4. K. N. Makarov
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  5. V. I. Bakhmutov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1318–1325, June, 1986.

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Snegirev, V.F., Galakhov, M.V., Petrov, V.A. et al. Polyfluorinated anions and cations — Intermediates in reactions of fluorine-containing vinyl ethers. Russ Chem Bull 35, 1194–1200 (1986). https://doi.org/10.1007/BF00956597

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  • DOI: https://doi.org/10.1007/BF00956597

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