Conclusions
Condensation of perfluoroisobutylene with perfluorovinyl alkyl ethers with CsF catalysis takes place according to a scheme of concerted nueleophilic addition, with participation of the perfluoro-tert-butyl anion as nucleophile and perfluoroisobutylene as electrophile. In the presence of CO2 the product of concerted perfluoroalkylcarboxylation forms.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1310–1312, June, 1986.
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Postovoi, S.A., Zeifman, Y.V. & Knunyants, I.L. Condensation of perfluoroisobutylene with perfluorinated vinyl alkyl ethers. Russ Chem Bull 35, 1186–1189 (1986). https://doi.org/10.1007/BF00956594
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DOI: https://doi.org/10.1007/BF00956594