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Reaction of vicinal dihalopolyfluoroalkanes with sodium azide

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of vicinal dihalopolyfluoroalkanes and related compounds with sodium azide causes replacement of halogen by an azide group, probably by an ionic cleavageaddition chain mechanism.

  2. 2.

    Nucleophilic azidobromination of fluoroolefins has been carried out by the action of sodium azide and bromine.

  3. 3.

    These reactions were used to synthesize new β-halopolyfluoroalkyl azides.

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Literature cited

  1. V. F. Cherstkov, S. A. Postovoi, L. T. Lantseva, S. R. Sterlin, Yu. V. Zeifman, and L. S. German, Izv. Akad. Nauk SSSR, Ser. Khim., 2740 (1984).

  2. S. A. Postovoi, L. T. Lantseva, Yu. V. Zeifman, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2531 (1982).

  3. Ya. Ch.-V. Kim, A. A. Glazkov, A. V. Ignatenko, S. P. Krukovskii, and V. A. Ponomarenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2319 (1984).

  4. X. Li, H. Pan, and X. Jiang, Tetrahedron Lett.,25, 4937 (1984).

    Google Scholar 

  5. I. Rico and C. J. Wakselman, J. Fluor. Chem.,20, 759 (1982).

    Google Scholar 

  6. S. P. Khrlakyan, Dissertation, Moscow (1966).

  7. R. E. Banks and M. J. McGlinchey, J. Chem. Soc. C. 3971 (1971).

  8. R. S. Atkinson, in: General Organic Chemistry [Russian translation], Vol. 3, Khimiya, Moscow (1982), p. 313.

    Google Scholar 

  9. C. G. Krespan, F. A. Van Catledge, and B. E. Smart, J. Am. Chem. Soc.,106, 5544 (1984).

    Google Scholar 

  10. I. L. Knunyants and É. G. Bykhovskaya, Dokl. Akad. Nauk SSSR,131, 1338 (1960).

    Google Scholar 

  11. R. E. Banks, D. Berry, M. J. McGlinchey, and G. J. Moore, J. Chem. Soc. C, 1017 (1970).

  12. S. P. Makarov, A. Ya. Yakubovich, A. S. Filatov, M. A. Énglin, and T. Ya. Nikiforova, Zh. Obshch. Khim.,38, 709 (1968).

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    S. A. Postovoi, Yu. V. Zeifman & I. L. Knunyants

Authors
  1. S. A. Postovoi
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  2. Yu. V. Zeifman
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  3. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 3306–1310, June, 1986.

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Postovoi, S.A., Zeifman, Y.V. & Knunyants, I.L. Reaction of vicinal dihalopolyfluoroalkanes with sodium azide. Russ Chem Bull 35, 1183–1186 (1986). https://doi.org/10.1007/BF00956593

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  • DOI: https://doi.org/10.1007/BF00956593

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