Conclusions
-
1.
A comparative19F NMR study of a series of model ArN(X)SO2C6H4F-4 compounds (X=H, HgPh, and Na) showed that the mechanism for the transmission of the substituent electronic effects in these compounds depends on the polarity of the Nδ−-Xδ+ bond. An increase in this polarity leads to an increase in the relative contribution of direct polar conjugation.
-
2.
The specific solvation of the mercury atom in the binuclear bridging N(HgPh)SO2 group has only a slight effect on its transmission capacity.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
S. I. Pombrik, E. V. Polunkin, A. S. Peregudov, É. I. Fedin, and D. N. Kravtsov, Izv. Akad. Nauk SSSR, Ser. Khim., 1289 (1982).
S. I. Pombrik, E. V. Polunkin, A. S. Peregudov, É. I. Fedin, and D. N. Kravtsov, Izv. Akad. Nauk SSSR, Ser. Khim., 900 (1985).
P. R. Wells, E. Ehrenson, and R. W. Taft, Prog. Phys. Org. Chem.,6, 204 (1968).
W. F. Reynolds, Prog. Phys. Org. Chem.,14, 165 (1983).
G. Dauphin, A. Kergomard, and H. Veschambre, Bull Soc. Chim. France, 3395 (1967).
A. E. Lutskii and I. K- Ishchenko, Zh. Obshch. Khim.,38, 1618 (1967).
E. Ehrenson, R. T. C. Browolee, and R. W. Taft, Prog. Phys. Org. Chem., 1 (1973).
K. Dimroth, R. Christian, I. Siepmann, and F. Bohlmann, Lieb. Ann. Chem.,663, 1 (1963).
E. N. Huntress and F. H. Carten, J. Am. Chem. Soc.,62, 511 (1940).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1263–1267, June, 1986.
Rights and permissions
About this article
Cite this article
Pombrik, S.I., Golovchenko, L.S., Peregudov, A.S. et al. 19F NMR Study of the transmission capacity of binuclear-N(X)SO2-bridging groups. Russ Chem Bull 35, 1144–1148 (1986). https://doi.org/10.1007/BF00956584
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00956584