Skip to main content
SpringerLink
Log in

Mechanism of the oxidation of acetylacetone by hydrogen peroxide, catalyzed by Mo(VI) complexes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Oxidation of the acetylacetonate ion in the coordination sphere of molybdenum(VI) by hydrogen peroxide proceeds without the participation of paramagnetic particles, recordable by steady-state ESR methods.

  2. 2.

    It was established by the PMR method that the oxidation of 2,4-pentanedione by hydrogen peroxide in the presence of sodium molybdate proceeds through intermediate formation of the complex of Mo(VI) with 3,3-dihydroxy-2,4-pentanedione.

  3. 3.

    A complex of Mo(VI) with 3,3-dihydroxy-2,4-pentanedione was produced for the first time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. I. I. Moiseev, Zh. Vses. Khim. O-va.,22, 30 (1977).

    Google Scholar 

  2. O. Bortolini, F. Difia, Ch. Scardellato, and P. Sermin, J. Mol, Catal.,11, 107 (1981).

    Google Scholar 

  3. I. I. Moiseev, V. A. Bochkareva, A. E. Gekhman, Yu. V. Kokunov, and Yu. A. Buslaev, Dokl. Akad. Nauk SSSR,233, 375 (1977).

    Google Scholar 

  4. J. T. Spence, Coord. Chem. Rev.,48, 59 (1983).

    Google Scholar 

  5. M. Calvin and C. L. Wood, J. Am. Chem. Soc.,62, 3152 (1940).

    Google Scholar 

  6. A. J. Gordon and R. A. Ford, The Chemist's Companion: A Handbook of Practical Data, Techniques and References, Wiley (1972).

  7. A. I. Busev, Analytical Chemistry of Molybdenum [in Russian], Izd, Akad. Nauk SSSR, Moscow (1962), p. 230.

    Google Scholar 

  8. G. Hesse and H. Stahl, Chem. Ber.,89, 2114 (1956).

    Google Scholar 

  9. B. M. Craven, K. G. Rameg, and W. B. Wise, Inorg. Chem.,10, 2626 (1971).

    Google Scholar 

  10. Yu. A. Buslaev, Yu. V. Kokunov, M. L. Gustyakova, Yu. D. Chubar, and I. I. Moiseev, Dokl. Akad. Nauk SSSR,233, 357 (1977).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    A. E. Gekhman, V. M. Nekipelov, S. G. Sakharov, K. I. Zamaraev & I. I. Moiseev

  2. Institute of Catalysis, Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk

    A. E. Gekhman, V. M. Nekipelov, S. G. Sakharov, K. I. Zamaraev & I. I. Moiseev

Authors
  1. A. E. Gekhman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Nekipelov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. G. Sakharov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. I. Zamaraev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. I. Moiseev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1242–1246, June, 1986.

The authors are grateful to E. P. Talzl for recording the ESR. spectra.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gekhman, A.E., Nekipelov, V.M., Sakharov, S.G. et al. Mechanism of the oxidation of acetylacetone by hydrogen peroxide, catalyzed by Mo(VI) complexes. Russ Chem Bull 35, 1126–1130 (1986). https://doi.org/10.1007/BF00956580

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00956580

Keywords

Search

Navigation