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Formation of the σ-acetonyl Pt(IV) complex in the reaction of iodoacetone with PtCl 2−4 in aqueous solution

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of K2PtCl4 with iodoacetone in aqueous solution at about 20‡C gives the σ-acetonyl Pt(IV) complex which is more stable to the action of nucleophilic reagents than the analogous methyl and ethyl complexes.

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Literature cited

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Authors and Affiliations

  1. Institute of Physical Organic Chemistry and Coal Chemistry, Academy of Sciences of the Ukrainian SSR, Donetsk

    V. V. Zamashchikov, E. S. Rudakov, S. A. Mitchenko, G. V. Nizova, A. N. Kitaigorodskii & G. B. Shul'pin

  2. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. V. Zamashchikov, E. S. Rudakov, S. A. Mitchenko, G. V. Nizova, A. N. Kitaigorodskii & G. B. Shul'pin

Authors
  1. V. V. Zamashchikov
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  2. E. S. Rudakov
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  3. S. A. Mitchenko
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  4. G. V. Nizova
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  5. A. N. Kitaigorodskii
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  6. G. B. Shul'pin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1657–1660, July, 1984.

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Zamashchikov, V.V., Rudakov, E.S., Mitchenko, S.A. et al. Formation of the σ-acetonyl Pt(IV) complex in the reaction of iodoacetone with PtCl 2−4 in aqueous solution. Russ Chem Bull 33, 1520–1522 (1984). https://doi.org/10.1007/BF00956545

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  • DOI: https://doi.org/10.1007/BF00956545

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