Dissociative electron capture by sulfide, sulfoxide, and sulfone molecules

  • V. I. Khvostenko
  • I. I. Furlei
  • V. K. Mavrodiev
  • G. V. Leplyanin
  • A. R. Derzhinskii
Brief Communications

Conclusions

The low energy resonance in the negative ion mass spectra of alkyl vinyl, 2,3-epoxypropyl alkyl, and 2, 3-epithiopropyl alkyl sulfies and their sulfoxide and sulfone analogs is related to electron capture in the σ* orbital of the S-C bond. The oxidation state of the sulfur atom has no qualitative effect on the major processes involved in the formation of the negative ions.

Keywords

Sulfone Sulfide Mass Spectrum Vinyl Oxidation State 

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Literature cited

  1. 1.
    V. I. Khvostenko, I. Kh. Aminev, and I. I. Furlei, Teor. Éksp. Khim,9, 99 (1973).Google Scholar
  2. 2.
    V. I. Khvostenko, Negative Ion Mass Spectrometry in Organic Chemistry [in Russian], Izd. Nauka, Moscow (1981), p. 103.Google Scholar
  3. 3.
    V. I. Khvostenko, V. V. Mazunov, V. S. Fal'ko, O. G. Khvostenko, and B. Sh. Chanbarisov, Khim. Fiz., 915 (1982).Google Scholar

Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • V. I. Khvostenko
    • 1
    • 2
  • I. I. Furlei
    • 1
    • 2
  • V. K. Mavrodiev
    • 1
    • 2
  • G. V. Leplyanin
    • 1
    • 2
  • A. R. Derzhinskii
    • 1
    • 2
  1. 1.Institute of Chemistry, Bashkir BranchAcademy of Sciences of the USSRUfa
  2. 2.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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