Dissociative electron capture by sulfide, sulfoxide, and sulfone molecules
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The low energy resonance in the negative ion mass spectra of alkyl vinyl, 2,3-epoxypropyl alkyl, and 2, 3-epithiopropyl alkyl sulfies and their sulfoxide and sulfone analogs is related to electron capture in the σ* orbital of the S-C bond. The oxidation state of the sulfur atom has no qualitative effect on the major processes involved in the formation of the negative ions.
KeywordsSulfone Sulfide Mass Spectrum Vinyl Oxidation State
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