Conclusions
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l.
A preparative method has been developed for the synthesis of 1-isocyanato-carboranes, by reaction of carboranecarbonyl chlorides with trimethylsilyl azide.
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2.
1-Isocyanatocarboranes display properties characteristic of aliphatic and aromatic isocyanates.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1644–1646, July, 1984.
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Kalinin, V.N., Astakhin, A.V., Kazantsev, A.V. et al. Synthesis of 1-isocyanatocarboranes. Russ Chem Bull 33, 1508–1510 (1984). https://doi.org/10.1007/BF00956540
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DOI: https://doi.org/10.1007/BF00956540