Skip to main content
SpringerLink
Log in

Kinetic laws for radical formation from n-butylacetamide hydroperoxide in dimethylacetamide medium

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In N, N-dimethylacetamide (DMA) medium, N-butylacetamide hydroperoxide (HNB) decomposes thermally to radicals according to the equationv i=k i [HNB]0/[DMA]0. Additions of o-dichlorobenzene to the system lead to a sharp increase in ki.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. T. I. Drozdova, A. L. Aleksandrov, and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 965 (1978).

  2. T. I. Drozdova, A. L. Aleksandrov, and E. T. Denisov, Izv. Akad. SSSR, Ser. Khim., 1212 (1978).

  3. A. L. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim., 2223 (1982).

  4. H. C. Bailey and G. W. Godin, Trans. Faraday Soc.,52, 68 (1956).

    Google Scholar 

  5. N. N. Pozdeeva, T. I. Sapacheva, and A. L. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim., 1738 (1976).

  6. V. M. Solyanikov, L. V. Petrov, and Kh. É. Kharlampidi, Dokl. Akad. Nauk SSSR,223, 1412 (1975).

    Google Scholar 

  7. J. A. Howard, Adv. Free Radical Chem.,4, 49 (1972).

    Google Scholar 

  8. N. M. Émanuel', G. E. Zaikov, and Z. K. Maizus, Role of the Medium in Radical Chain Oxidation Reactions of Organic Compounds [in Russian], Nauka, Moscow (1973), pp. 141, 106.

    Google Scholar 

  9. T. I. Drozdova, A. L. Aleksandrov, and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 967 (1978).

  10. A. L. Aleksandrov, T. I. Drozdova, and E. T. Denisov, Abstracts of the Seventh All-Union Conference on the Chemistry of Organic Peroxides [in Russian], Volgograd (1980), p. 134.

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    A. L. Aleksandrov

Authors
  1. A. L. Aleksandrov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1638–1641, July, 1984.

The author thanks M. F. Semenov for help in carrying out the experimental part of the work.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aleksandrov, A.L. Kinetic laws for radical formation from n-butylacetamide hydroperoxide in dimethylacetamide medium. Russ Chem Bull 33, 1502–1505 (1984). https://doi.org/10.1007/BF00956538

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00956538

Keywords

Search

Navigation