Conclusions
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1.
Methods for the synthesis of ortho-esters based on 3, 6-di-tert-butylpyrocatechol have been developed.
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2.
Concepts on the mechanisms of formation of orthoformate and orthocarbonate in the reaction of 3, 6-di-tert-butylpyrocatechol with chloroform and carbon tetrachloride in two-phase catalytic systems have been formulated.
Literature cited
V. B. Vol'eva, I. S. Belostotskaya, I. A. Novikova, É. V. Dzhuaryan, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 2414 (1980).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1632–1635, July, 1984.
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Vol'eva, V.B., Prokof'eva, T.I., Novikova, I.A. et al. Ortho-esters based on 3, 6-di-tertbutylpyrocatechol. Russ Chem Bull 33, 1497–1500 (1984). https://doi.org/10.1007/BF00956536
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DOI: https://doi.org/10.1007/BF00956536