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Oxidation of metallic copper and silver by orthoquinones in organic solvents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The oxidative addition of substituted o-quinones to metallic copper and silver in organic solvents was investigated. The effect of the nature of the o-quinone, the organic solvent, and the complexing additives (o-phenanthroline, 2,2'-bipyridyl, isonltriles, and alkenes) on the reaction was investigated.

  2. 2.

    The investigated dissolution reactions of metallic copper provide a convenient method for the production of the o-semiquinolate and catecholate complexes of Cu(I) and Cu(II) in preparative quantities.

  3. 3.

    The reversible photodissociation and thermal dissociation of the series of synthesized compounds in solution were investigated.

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, Gor'kii

    G. A. Abakumov, V. K. Cherkasov, A. V. Lobanov & G. A. Razuvaev

Authors
  1. G. A. Abakumov
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  2. V. K. Cherkasov
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  3. A. V. Lobanov
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  4. G. A. Razuvaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1610–1618, July, 1984.

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Abakumov, G.A., Cherkasov, V.K., Lobanov, A.V. et al. Oxidation of metallic copper and silver by orthoquinones in organic solvents. Russ Chem Bull 33, 1478–1485 (1984). https://doi.org/10.1007/BF00956531

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  • DOI: https://doi.org/10.1007/BF00956531

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