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Factors determining transformations of silicon-containing aroxyls Communication 1. Disproportionation and dimerization-rearrangement as alternative transformation paths of silicon-containing aroxyls

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The character of the transformations of silicon-containing phenoxyl radicals depends on both the type of the alkyl substituent (disproportionation in the case of para-methyl group, dimerization-rearrangement in the case of para-isopropyl and para-cyclohexyl groups) and type of organosilyl substituent (dimerization-rearrangement in the case of ortho-trimethylsilyl group, disproportionation in the case of ortho-triethylsilyl and orthotriphenylsilyl groups).

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Literature cited

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Translated from Izvestiya Akademii Nauk USSR, Seriya Khimicheskaya, No. 7, pp. 1607–1609, July, 1984.

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Muslin, D.V., Lyapina, N.S. Factors determining transformations of silicon-containing aroxyls Communication 1. Disproportionation and dimerization-rearrangement as alternative transformation paths of silicon-containing aroxyls. Russ Chem Bull 33, 1475–1477 (1984). https://doi.org/10.1007/BF00956530

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  • DOI: https://doi.org/10.1007/BF00956530

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