Conclusions
The character of the transformations of silicon-containing phenoxyl radicals depends on both the type of the alkyl substituent (disproportionation in the case of para-methyl group, dimerization-rearrangement in the case of para-isopropyl and para-cyclohexyl groups) and type of organosilyl substituent (dimerization-rearrangement in the case of ortho-trimethylsilyl group, disproportionation in the case of ortho-triethylsilyl and orthotriphenylsilyl groups).
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G. A. Razuvaev, N. S. Vasileiskaya, and D. V. Muslin, Dokl. Akad. Nauk SSSR,175, 620 (1967).
V. V. Ershov, G. A. Nikiforov, and A. A. Volod'kin, Sterically Hindered Phenols [in Russian], Khimiya, Moscow (1972), pp. 90–168.
G. A. Razuvaev, I. L. Khrzhanovskaya, N. S. Vasileiskaya, and D. V. Muslin, Dokl. Akad. Nauk SSSR,177, 600 (1967).
D. V. Muslin, N. Sh. Lyapina, E. S. Klimov, V. G. Kirilicheva, and G. A. Razuvaev, Izv. Akad. Nauk SSSR., Ser. Khim., 1385 (1980).
G. A. Razuvaev, N. S. Vasileiskaya, and N. N. Vavilina, J. Organomet. Chem.,80, 19 (1974).
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Translated from Izvestiya Akademii Nauk USSR, Seriya Khimicheskaya, No. 7, pp. 1607–1609, July, 1984.
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Muslin, D.V., Lyapina, N.S. Factors determining transformations of silicon-containing aroxyls Communication 1. Disproportionation and dimerization-rearrangement as alternative transformation paths of silicon-containing aroxyls. Russ Chem Bull 33, 1475–1477 (1984). https://doi.org/10.1007/BF00956530
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DOI: https://doi.org/10.1007/BF00956530