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Synthesis of Ω-mercuri- and and Ω-lithioalkylbenzenechromiumtricarbonyls

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Reaction of [Ph(CH2)n]2Hg (n=3, 4) with (NH3)3Cr(CO)3 or Cr(CO)6 affords the corresponding mono- and binuclear arenechromium tricarbonyl derivatives.

  2. 2.

    Treatment of the complexes [Ph(CH2)n]2Hg · [Cr(CO)3]2 with mercuric chloride gives the Ω-chloromercuri-substituted arenechromium tricarbonyls (CO)3Cr·Ph(CH2)n]2HgCl (n=3, 4), in which the mercury atom is not coordinated with the Cr(CO)6 groups.

  3. 3.

    The formation ofΩ-lithioalkylbenzenechromium tricarbonyls from theΩ-bromo compounds (CO)3Cr Ph(CH2)n]2Br (n=2,4) by standard methods proceeds with difficulty, and is accompanied by a number of byproducts.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. S. Kaganovich & M. I. Rybinskaya

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  1. V. S. Kaganovich
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  2. M. I. Rybinskaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1601–1606, July, 1984.

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Kaganovich, V.S., Rybinskaya, M.I. Synthesis of Ω-mercuri- and and Ω-lithioalkylbenzenechromiumtricarbonyls. Russ Chem Bull 33, 1471–1475 (1984). https://doi.org/10.1007/BF00956529

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  • DOI: https://doi.org/10.1007/BF00956529

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