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Catalytic phosphorylation of polyfluoroalkyl alcohols Communication 8. Synthesis and stereochemistry of bis(α-trifluoromethyl-m-trifluoromethylbenzyl) chlorophosphate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Catalytic phosphorylation ofα-trifluoromethyl-m-trifluoromethylbenzyl alcohol by POCl3 in the ratio of 2∶1 primarily yielded bis (α-trifluoromethyl)m-trifluoromethylbenzyl)chlorophosphate regardless of the conditions of the reaction, and in contrast to unsubstitutedα-trifluoromethylbenzyl alcohol, absolutely no simple benzyl ether was formed.

  2. 2.

    The bis(α-trifluoromethyl-m-trifluoromethylbenzyl) chlorophosphate obtained is a mixture of three diastereomers in a ratio close to the statistical ratio.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    E. I. Goryunov, L. S. Zakharov, P. V. Petrovskii & M. I. Kabachnik

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  1. E. I. Goryunov
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  2. L. S. Zakharov
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  3. P. V. Petrovskii
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  4. M. I. Kabachnik
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1593–1597, July, 1984.

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Goryunov, E.I., Zakharov, L.S., Petrovskii, P.V. et al. Catalytic phosphorylation of polyfluoroalkyl alcohols Communication 8. Synthesis and stereochemistry of bis(α-trifluoromethyl-m-trifluoromethylbenzyl) chlorophosphate. Russ Chem Bull 33, 1463–1466 (1984). https://doi.org/10.1007/BF00956527

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  • DOI: https://doi.org/10.1007/BF00956527

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