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Raman spectra of nitric acid in aqueous sulfuric acid solutions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The relative concentrations of NO2 + ions have been calculated for low concentrations of nitric acid (0.1–0.3 M), using internal standards.

  2. 2.

    A procedure is proposed for the calculation of NO2 + ion concentrations in sulfuric acid-nitric acid-water systems with high concentrations of HNO3 in the system, and values have been calculated for the equilibrium concentrations of NO2 + in solutions containing up to 6.8 M nitric acid.

  3. 3.

    A single curve has been plotted for the ionization of nitric acid in aqueous sulfuric acid solutions; the correctness of the scheme that has been adopted for the ionization of nitric acid has been verified.

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Literature cited

  1. R. J. Gillespie, J. Graham, E. D. Hudges, C. K. Ingold, and E. R. A. Recling, J. Chem. Soc., 2504 (1950).

  2. J. Chedin, Ann. Chim. (Paris),8, 243 (1937).

    Google Scholar 

  3. T. Goddard and C. K. Ingold, J. Chem. Soc., 2559 (1950).

  4. J. Cox, B. Jeffery, and M. Gruter, Nature,162, 259 (1948).

    Google Scholar 

  5. N. C. Marziano, P. G. Traverso, A. De Santis, and M. Sampoli, J. Chem. Soc., Chem. Commun., 873 (1978).

  6. N. B. Librovich, P. I. Valov, and M. I. Vinnik, Zh. Fiz. Khim.,41, 2094 (1967).

    Google Scholar 

  7. Yu. V. Karyakin and I. I. Angelov, Pure Chemical Reagents [in Russian], Moscow (1974), p. 162.

  8. The Chemist's Handbook [in Russian], GONTI, Leningrad-Moscow (1952), Vol. 3, p. 363.

  9. The Chemist's Handbook [in Russian], GONTI, Leningrad-Moscow (1952), Vol. 3, p. 376.

  10. N. G. Zarakhani, N. B. Librovich, and M. I. Vinnik, Zh. Fiz. Khim.,45, 1733 (1971).

    Google Scholar 

  11. A. G. Zhigulin, N. B. Librovich, G. F. Burya, and M. I. Vinnik, Zh. Org. Khim.,15, No. 3, 595 (1979).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    N. B. Librovich, B. V. Rassadin, I. M. Medvetskaya, L. R. Andreeva & M. I. Vinnik

  2. Scientific-Research Institute of the Nitrogen Industry and Products of Organic Synthesis, Moscow

    N. B. Librovich, B. V. Rassadin, I. M. Medvetskaya, L. R. Andreeva & M. I. Vinnik

Authors
  1. N. B. Librovich
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  2. B. V. Rassadin
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  3. I. M. Medvetskaya
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  4. L. R. Andreeva
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  5. M. I. Vinnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1524–1530, July, 1984.

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Librovich, N.B., Rassadin, B.V., Medvetskaya, I.M. et al. Raman spectra of nitric acid in aqueous sulfuric acid solutions. Russ Chem Bull 33, 1401–1405 (1984). https://doi.org/10.1007/BF00956514

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  • DOI: https://doi.org/10.1007/BF00956514

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