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Magnetic interactions in copper(II) complexes with derivatives of nitroxyl radical of imidazoline

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Programs have been wirtten for calculation of the line form in anisotropic ESR spectra of copper-radical complexes in the triplet and quartet states. Feasibility has been demonstrated for the use of ESR to identify metal-radical complexes and to determine their geometric characteristics.

  2. 2.

    The fine structure observed in the anisotropic ESR spectra has been analyzed. It has been shown that along with dipole-dipole interaction, the anisotropic component of exchange interaction makes a substantial contribution to the fine structure.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    E. G. Boguslavskii, A. A. Shklyaev, V. F. Yudanov, V. I. Ovcharenko & S. V. Larionov

  2. Institute of Chemistry and Chemical Technology, Siberian Branch, Academy of Sciences of the USSR, Krasnoyarsk

    E. G. Boguslavskii, A. A. Shklyaev, V. F. Yudanov, V. I. Ovcharenko & S. V. Larionov

Authors
  1. E. G. Boguslavskii
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  2. A. A. Shklyaev
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  3. V. F. Yudanov
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  4. V. I. Ovcharenko
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  5. S. V. Larionov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1517–1524, July, 1984.

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Boguslavskii, E.G., Shklyaev, A.A., Yudanov, V.F. et al. Magnetic interactions in copper(II) complexes with derivatives of nitroxyl radical of imidazoline. Russ Chem Bull 33, 1394–1400 (1984). https://doi.org/10.1007/BF00956513

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  • DOI: https://doi.org/10.1007/BF00956513

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