Conclusions
-
1.
It has been shown for the first time by means of1H NMR that in solutions of cyclic compounds of trivalent antimony, dimeric structures with the participation, of endocyclic and exocyclic O atoms are realized. The molecular dynamics are determined by conformational conversions and also by the process of rupture and formation of dimeric bridge bonds Sb...O, this process of bond rupture and formation being the limiting stage of the overall process. The process mechanism has been established, and the energetics have been estimated.
-
2.
The dominant conformations in the monomeric form have been determined, and the characteristics of the1H and13C NMR spectra are given for the particular compounds that have been studied.
Similar content being viewed by others
Literature cited
B. A. Arbuzov, Yu. Yu. Samitov, and Yu. M. Mareev, Dokl. Akad. Nauk SSSR,219, 863 (1974).
B. A. Arbuzov, V. V. Klochov, A. V. Aganov, Yu. M. Mareev, and Yu. Yu. Samitov, Izv. Akad. Nauk SSSR, Ser. Khim., 1687 (1980).
B. A. Arbuzov, V. V. Klochov, A. V. Aganov, Yu. Yu. Samitov, Yu. M. Mareev, and V. S. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim., 529 (1983).
Yu. Yu. Samitov, Dokl. Akad. Nauk SSSR,164, 347 (1965).
B. A. Arbuzov, E. N. Klimovitskii, V. V. Klochkov, I. V. Anonimova, and A. V. Aganov, Zh. Obshch. Khim.,53, 442 (1983).
B. A. Arbuzov, R. A. Kadyrov, V. V. Klochkov, R. P. Arshinova, and A. V. Aganov, Izv. Akad. Nauk SSSR, Ser. Khim., 588 (1982).
Yu. Yu. Samitov, N. K. Tazeeva, N. A. Chadaeva, and G. Kh. Kamai, Khim. Geterotsikl. Soedin., 457 (1973).
D. W. Aksness, Acta Chem. Scand. A,28, 1175 (1974).
D. W. Aksness, Acta Chem. Scand. A,31, 845 (1977).
G. W. Koeppl, D. S. Sagatys, G. S. Krishnamurty, and S. Miller, J. Am. Chem. Soc.,89, 3396 (1967).
J. Jacobus, Chem. Commun., 1059 (1971).
W. Egan, R. Tang, Gi Zon, and K. Mislow, J. Am. Chem. Soc.,93, 6205 (1971).
J. P. Albrand, J. P. Dutasta, and J. B. Robert, J. Am. Chem. Soc.,96, 4584 (1974).
H. Meyer, J. Klein, and A. Meiss, J. Organomet. Chem.,177, 323 (1979).
J. P. Dutasta, A. Grand, A. C. Guimaraes, and J. B. Robert, Tetrahedron.35, 197 (1979).
C. Burschka, Z. Anorg. Allg. Chem.,446, 185 (1978).
B. A. Arbuzov, V. S. Vinogradova, R. R. Shagidullin, Yu. M. Mareev, and I. Kh. Shakirov, Izv. Akad. Nauk SSSR, Ser. Khim., 390 (1976).
B. A. Arbuzov, Yu.M. Mareev, and V. S. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim., 170 (1979).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1501–1510, July, 1984.
Rights and permissions
About this article
Cite this article
Arbuzov, B.A., Aganov, A.V., Klochkov, V.V. et al. Contribution of intermolecular associates and inversion of pyramid of antimony bonds in conformational exchange of certain 1,3,2-dioxastibinanes and 1,3,2-dioxastibepines. Russ Chem Bull 33, 1380–1388 (1984). https://doi.org/10.1007/BF00956511
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00956511