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Trifluoroacetolysis of 2-bromoethyl-2,2-d2 nosylate

  • T. A. Smolina
  • E. D. Gopius
  • A. R. Gromov
  • R. D. Rakhimov
  • O. A. Reutov
Physical Chemistry
  • 23 Downloads

Conclusions

PMR spectroscopy has been used to investigate the kinetics of trifluoroacetolysis of 2-bromoethyl-2,2-d2 nosylate and the effects on the rate constant from adding lithium perchlorate or lithium nosylate. It has been shown that the reaction is accompanied by isomerization of the original sulfate (1,2-migration of the bromine) and that the reaction is accomplished through an ion-pair mechanism with the participation of contact ion pairs and free ions.

Keywords

Sulfate Spectroscopy Lithium Perchlorate Bromine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • T. A. Smolina
    • 1
  • E. D. Gopius
    • 1
  • A. R. Gromov
    • 1
  • R. D. Rakhimov
    • 1
  • O. A. Reutov
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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