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Kinetics of the decomposition of α-hydroxyethylperacetate catalyzed by cobalt acetate

  • M. G. Vinogradov
  • M. L. Gringol'ts
  • B. S. Strel'chik
  • G. I. Nikishin
Physical Chemistry

Conclusions

  1. 1.

    The mechanism of the reaction, consisting of homolytic decomposition of two molecules of peroxide in the coordination sphere of Co(III), was proposed based on the study of the kinetics of decomposition of α-hydroxethylperacetate catalyzed by cobalt acetate in a solution of acetaldehyde.

     
  2. 2.

    In the thermal decomposition of α-hydroxyethylperacetate, a homolytic reaction of decomposition of the peroxide with liberation of CH4, and CO2 takes place in addition to the monomolecular heterolytic reaction of formation of acetic acid.

     

Keywords

Acetate Acetaldehyde Peroxide Acetic Acid Cobalt 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • M. G. Vinogradov
    • 1
    • 2
  • M. L. Gringol'ts
    • 1
    • 2
  • B. S. Strel'chik
    • 1
    • 2
  • G. I. Nikishin
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.Novokuibyshevsk Branch of the Scientific-Research Institute of Organic SynthesisUSSR

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