Conclusion
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1.
Synthesized 1,4-bis(triethylsiloxybutoxytitanoxydimethylsilyl)-benzenes disproportionate on heating to form triethylbutoxysilane. The reaction follows a first-order kinetic rate equation.
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2.
An increase in the number of triethylsiloxy groups leads to increased oligomer thermal stability.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1116–1120, May, 1987.
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Khrustaleva, E.A., Fridman, L.I. & Suvorov, A.L. Synthesis and disproportionation of 1,4-bis(triethylsiloxybutoxytitanoxydimethylsilyl)benzenes. Russ Chem Bull 36, 1032–1035 (1987). https://doi.org/10.1007/BF00956362
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DOI: https://doi.org/10.1007/BF00956362