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Regioselective hydroalumination of unsaturated hydrocarbons by alkylalanes catalyzed by zirconium complexes

  • U. M. Dzhemilev
  • A. G. Ibragimov
  • O. S. Vostrikova
  • E. V. Vasil'eva
  • G. A. Tolstikov
Organic Chemistry

Conclusion

An effective method has been developed for the preparation of difficultly accessible higher dialkylhaloalanes by hydroalumination of mono-, di-, and tri-olefins of different structures by i-Bu2AlCl in the presence of Cp2ZrCl2.

Keywords

Zirconium Hydrocarbon Unsaturated Hydrocarbon Cp2ZrCl2 Zirconium Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    U. M. Dzhemilev, O. S. Vostrikova, A. G. Ibragimov, G. A. Tolstikov, and L. M. Zelenova, Izv. Akad. Nauk SSSR, Ser. Khim., 476 (1981).Google Scholar
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    N. N. Korneev, Chemistry and Technology of Organoaluminum Compounds [in Russian], Khimiya, Moscow (1979), p. 247.Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • U. M. Dzhemilev
    • 1
  • A. G. Ibragimov
    • 1
  • O. S. Vostrikova
    • 1
  • E. V. Vasil'eva
    • 1
  • G. A. Tolstikov
    • 1
  1. 1.Institute of Chemistry, Bashkir BranchAcademy of Sciences of the USSRUfa

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