Effect of the nature of the lipid and viologen on transmembrane electron transfer in the vesicular photosystem: electron donor-Ru(bipy) 3 2+ -viologen-oxidant

  • E. E. Yablonskaya
  • V. Ya. Shafirovich
Physical Chemistry
  • 25 Downloads

Conclusions

  1. 1.

    The break in the temperature dependence of the transmembrane electron transfer rate constant (in Arrhenius coordinates) corresponds to the phase transition of the lipid from the gel to the liquid crystalline state.

     
  2. 2.

    The transmembrane electron transfer rate constant is not dependent on the structure of the electron carrier, the viologen.

     

Keywords

Lipid Phase Transition Electron Transfer Transfer Rate Bipy 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. Ya. Shafirovich, V. A. Kuz'min, P. P. Levin, and N. K. Khannanov, Dokl. Akad. Nauk SSSR,276, 921 (1984).Google Scholar
  2. 2.
    J. N. Braddock and T. J. Meyer, J. Am. Chem. Soc.,95, 3158 (1973).Google Scholar
  3. 3.
    W. A. Hynes, L. K. Yanowski, and M. Shiller, J. Am. Chem. Soc.,60, 3053 (1938).Google Scholar
  4. 4.
    E. E. Yablonskaya and V. Ya. Shafirovich, Nouv. J. Chim.,8, 117 (1984).Google Scholar
  5. 5.
    T. Nishijima, T. Nagamura, and T. Matsuo, J. Polym. Sci., Polym. Lett. Ed.,19, 65 (1981).Google Scholar
  6. 6.
    M. Eibl, D. Arnold, H. Wettsien, and O. Westphal, Lieb. Ann. Chem.,708, 226 (1967).Google Scholar
  7. 7.
    K. Kalyanasundaram, Coord. Chem. Rev.,244, 159 (1982).Google Scholar
  8. 8.
    H. J. Hinz and J. M. Sturtevant, J. Biol. Chem.,247, 6071 (1972).Google Scholar
  9. 9.
    B. D. Landbrooke, R. M. Williams, and D. Chapman, Biochim. Biophys. Acta,10, 177 (1968).Google Scholar
  10. 10.
    A. G. Lee, Biochim. Biophys. Acta,472, 237 (1977).Google Scholar
  11. 11.
    K. Kano, A. Romero, B. Djermouni et al., J. Am. Chem. Soc.,101, 4030 (1979).Google Scholar
  12. 12.
    V. é. Maier and V. Ya. Shafirovich, Dokl. Akad. Nauk SSSR,277, 125 (1984).Google Scholar
  13. 13.
    V. E. Maier and V. Ya. Shafirovich, Chem. Commun., 1063 (1985).Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • E. E. Yablonskaya
    • 1
  • V. Ya. Shafirovich
    • 1
  1. 1.Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka

Personalised recommendations