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Spin trapping study on addition reaction of organic radicals to methyl methacrylate and methyl tiglate

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Summary

The addition reaction of the radicals formed from 2,2∢zobisisobutyronitrile(AIBN), diisopropyloxydicarbonate(DISOP), or benzoyl peroxide(BPO) to methyl methacrylate-β-d2(MMA-β-d2) or methyl tiglate(MTA) has been investigated at 30°C by the spin trapping technique. The tail and head addition of the radicals were detected for MMA-β-d2, and only the tail addition was observed for MTA.

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Authors and Affiliations

  1. Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, 560, Osaka, Japan

    Mikiharu Kamachi, Yoko Kuwae & Shun -ichi Nozakura

Authors
  1. Mikiharu Kamachi
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  2. Yoko Kuwae
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  3. Shun -ichi Nozakura
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Kamachi, M., Kuwae, Y. & Nozakura, S.i. Spin trapping study on addition reaction of organic radicals to methyl methacrylate and methyl tiglate. Polymer Bulletin 6, 143–146 (1981). https://doi.org/10.1007/BF00956280

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  • DOI: https://doi.org/10.1007/BF00956280

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