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Oxidation of saturated hydrocarbons by tert-butyl hydroperoxide in the presence of transition metal compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The acetylacetonates of V(III), V(IV), Cr(III), and Co(II), the stearates and caproates of Cu(II), Mn(II), Fe(II), and Co(II), and the carbonyl derivatives of Cr, Mn, and Rh catalyze the selective oxidation of nonane, cyclohexane, and diphenylmethane by tert-butyl hydroperoxide to the isomeric ketones.

  2. 2.

    tert-Butoxyl radicals do not take part in the oxidation of hydrocarbons.

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Literature cited

  1. I. P. Skibida, Usp. Khim.,44, 1729 (1975); N. M. Émanuél, Neftekhimiya,18, 485 (1978); E. T. Denisov, Mechanism of Homolytic Cleavage of Molecules in the Liquid Phase, Advances in Science and Technology. Kinetics and Catalysis Series, Vol. 9 [in Russian], VINITI, Moscow (1981), pp. 126–130.

    Google Scholar 

  2. Z. K. Maizus, I. P. Skibida, and N. M. Émanuél, Dokl. Akad. Nauk SSSR,131, 880 (1960).

    Google Scholar 

  3. L. I. Matienko, I. P. Skibida, and Z. K. Maizus, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1322; V. N. Sapunov, Kh. M. Diall, V. G. Sharykin, and N. N. Lebedev, Kinet. Katal,19, 220 (1979).

  4. R. A. Sheldon and J. A. van Doorn, J. Catal,31, 427 (1973).

    Google Scholar 

  5. V. N, Glushakova, N. A. Skorodumova, J. V. Spirina, and G. A. Razuvaev, Abstracts of Twelfth Colloquium onOrganometallic Chemistry DDR-Poland, Potsdam (1980), p. 25; I. V. Spirina, V. N. Alyasov, N. A. Skorodumova, V. I. Glushakova, and G. A. Razuvaev, Abstracts of Second All-Union Conference on Organometallic Chemistry [in Russian], Gorki (1982), p. 188.

  6. A. Gordon and R. Ford, Chemist's Companion: A Handbook of Practical Data, Techniques and References, Wiley (1973).

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, Gorki

    V. N. Glushakova, N. A. Skorodumova, O. Yu. Gryzina & G. A. Razuvaev

Authors
  1. V. N. Glushakova
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  2. N. A. Skorodumova
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  3. O. Yu. Gryzina
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  4. G. A. Razuvaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1193–1195, May, 1983.

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Glushakova, V.N., Skorodumova, N.A., Gryzina, O.Y. et al. Oxidation of saturated hydrocarbons by tert-butyl hydroperoxide in the presence of transition metal compounds. Russ Chem Bull 32, 1078–1079 (1983). https://doi.org/10.1007/BF00956174

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  • DOI: https://doi.org/10.1007/BF00956174

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