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Salts of symmetric polynitropentanes and their reactions with halogens

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of 1,1,1,3,5,5,5-heptanitropentane and 1,5-difluoro-1,1,3,5,5-pentanitropentane in a nonpolar medium at a reduced temperature yields the ammonium, pyridinium, and anilinium salts of the polynitropentanes indicated.

  2. 2.

    The ability of the ammonium and pyridinium salts of 1,1,1,3,5,5,5-heptanitropentane and 1,5-difluoro-1,1,3,5,5-pentanitropentane to undergo chlorination and bromination to form the corresponding 3-chloro- and 3-bromo derivatives and of the ammonium salt of 1,5-difluoro-1,1,3,5,5-pentanitropentane in water to undergo fluorination to 1,3,5-trifluoro-1,1,3,5,5-pentanitropentane has been demonstrated.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    L. T. Eremenko, G. V. Oreshko & M. A. Fadeev

Authors
  1. L. T. Eremenko
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  2. G. V. Oreshko
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  3. M. A. Fadeev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1133–1136, May, 1983.

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Eremenko, L.T., Oreshko, G.V. & Fadeev, M.A. Salts of symmetric polynitropentanes and their reactions with halogens. Russ Chem Bull 32, 1024–1027 (1983). https://doi.org/10.1007/BF00956160

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  • DOI: https://doi.org/10.1007/BF00956160

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