Synthesis of several derivatives of trifluoromethyl alkyl sulfones

  • T. I. Cherkasova
  • V. M. Khutoretskii
  • L. V. Okhlobystina
Organic Chemistry


  1. 1.

    The nitration of trifluoromethanesulfonylacetic acid results in the formation of trifluoromethyl nitromethyl sulfone and its conversion product, viz., bis(trifluoromethanesulfonyl)furoxan.

  2. 2.

    The reaction of nitromalonic ester with trifluoromethanesulfenyl chloride yields trifluoromethanesulfenylnitromalonic ester, and its oxidation yields trifluoromethanesulfonylnitromalonic ester.

  3. 3.

    The reaction of trifluoromethanesulfonylmethylmagnesium bromide with bromoacetone results in the addition of the former to the carbonyl group.



Oxidation Chloride Ester Sulfone Bromide 
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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • T. I. Cherkasova
    • 1
  • V. M. Khutoretskii
    • 1
  • L. V. Okhlobystina
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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