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Complexing capability of some phosphine oxides containing a dimethylphosphinylmethyl group

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    TheνP=O absorption band of dimethyl (chloromethyl)-, dimethyl(methoxymethyl)- and dimethyl(phenoxymethyl)phosphine oxides is quite sensitive to complexation with a number of metal salts.

  2. 2.

    Complexation constants for these phosphine oxides with copper (II) chloride in acetonitrile have been estimated. The stability constants of the [CuClL]+complexes of I–III are close to one another.

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Authors and Affiliations

  1. Institute of Physiologically Active Substances, Academy of Sciences of the USSR, Chernogolovka

    O. A. Raevskii, T. I. Ignat'eva, V. P. Novikov, A. F. Solotnov, T. E. Kron & E. N. Tsvetkov

Authors
  1. O. A. Raevskii
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  2. T. I. Ignat'eva
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  3. V. P. Novikov
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  4. A. F. Solotnov
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  5. T. E. Kron
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  6. E. N. Tsvetkov
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Translated from Izvestiya Akademii Nauk USSR, Seriya Khimicheskaya, No. 5, pp. 1095–1101, May, 1983.

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Raevskii, O.A., Ignat'eva, T.I., Novikov, V.P. et al. Complexing capability of some phosphine oxides containing a dimethylphosphinylmethyl group. Russ Chem Bull 32, 991–995 (1983). https://doi.org/10.1007/BF00956152

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  • DOI: https://doi.org/10.1007/BF00956152

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