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F Kα x-ray fluorescence spectra of fluorinated aromatic compounds

  • V. D. Yumatov
  • G. G. Furin
  • A. V. Okotrub
  • I. A. Asanov
  • L. N. Mazalov
  • G. G. Yakobson
Physical Chemistry
  • 54 Downloads

Conclusions

The fluorine 2p AO in fluorine-containing aromatic compounds make a small contribution to theπ-type highest filled orbitals, but a somewhat larger one to the lowerπ-level system. The strongest interaction of the fluorine 2p electrons with the benzene ring occurs in theσ-level system.

Keywords

Benzene Fluorine Strong Interaction Fluorescence Spectrum Aromatic Compound 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    William A. Sheppard and Clay M. Sharts, Organic Fluorine Chemistry, W. A. Benjamin, New York.Google Scholar
  2. 2.
    W. C. Price, A. W. Potts, A. Gabriel, and T. A. Williams, in: A. R. West, ed., Molecular Spectroscopy, Heyden and Son, Ltd., London, The Institute of Petroleum (1977), pp. 381–395.Google Scholar
  3. 3.
    D. T. Clark, D. Kilcast, D. B. Adams, and W. K. R. Musgrave, J. Electron Spectrosc. Relat. Phenomena,1, 227 (1972/73).Google Scholar
  4. 4.
    J. M. Briggs and E. W. Randall, J. Chem. Soc., Perkin Trans., No. 2, 1789 (1973).Google Scholar
  5. 5.
    B. M. Mikhailov, Usp. Khim.,40, 2121 (1971).Google Scholar
  6. 6.
    I. B. Martynov, S. S. Dubov, and M. A. Landau, Zh. Vses. Khim. Obshch. im. D. I. Mendeleeva,12, 119 (1967).Google Scholar
  7. 7.
    E. Tegeler, G. Wiech, and Faessler, J. Phys., B: Atom. Molec. Phys.,13, 4771 (1980).Google Scholar
  8. 8.
    G. N. Dolenko, G. K. Parygina, and V. M. Karpov, Zh. Strukt. Khim.,7, 539 (1976).Google Scholar
  9. 9.
    V. I. Nefedov, The Use of X-ray Electron Spectroscopy in Chemistry. Molecular Structure and the Chemical Bond [in Russian), Vol. 1, Vses. Inst. Nauchn. Issled. Tekh. Inform. (VINITI), Moscow (1973), p. 862.Google Scholar
  10. 10.
    B. C. Trudell and S. J. W. Price, Can. J. Chem.,55, 1279 (1977).Google Scholar
  11. 11.
    B. C. Trudell and S. J. W. Price, Can. J. Chem.,56, 538 (1978).Google Scholar
  12. 12.
    J. M. Schilman and J. W. Moskowitz, J. Chem. Phys.,43, 3287 (1965).Google Scholar
  13. 13.
    J. Berkowitz, Chem. Phys. Lett.,11, 21 (1971).Google Scholar
  14. 14.
    F. I. Vilesov, ed., Advances in Photonics [in Russian], Izd. Leningrad. Inst., No. 5 (1975).Google Scholar
  15. 15.
    P. J. M. Neijzen and C. A. De Lange, J. Electron Spectrosc. ReIat. Phenomena,14, 187 (1979).Google Scholar
  16. 16.
    I. L. Knunyants and G. G. Yakobson, (eds.), OrganofluorineSyntheses [in Russian], Khimiya, Moscow (1973).Google Scholar

Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • V. D. Yumatov
    • 1
    • 2
  • G. G. Furin
    • 1
    • 2
  • A. V. Okotrub
    • 1
    • 2
  • I. A. Asanov
    • 1
    • 2
  • L. N. Mazalov
    • 1
    • 2
  • G. G. Yakobson
    • 1
    • 2
  1. 1.Institute of Inorganic Chemistry, Siberian BranchAcademy of Sciences of the USSRNovosibirsk
  2. 2.Novosibirsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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