Conclusions
The electron impact approach was used to investigate the processes of formation of positive and negative ions in the mass spectra of perchloryl fluoride and chlorosyl fluoride. The bond energies F-ClO, Cl-OF, O-ClF, O,O-Cl0F, O-Cl0[2F, and P-Cl03 have been calculated, as well as the heat of formation of Cl0F, the lower limits of electron affinity of the molecules OF, Cl02F, Cl02, and Cl03, and the ionization potential of the Cl03 molecules. The ionization potential of the Cl0F molecule was also measured.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
M. Cartwright and A. A. Woolf, J. Fluor. Chem.,13, 353 (1977).
R. L. Dekock, D. R. Lloyd, I. H. Hillier, and V. R. Sounders, Proc. Roy. Soc. London,A328, 401 (1972).
V. H. Dibeler, R. M. Reese, and D. E. Mann, J. Chem. Phys.,27, 176 (1957).
A. V. Baluev, Z. K. Nikitina, L. I. Fedorova, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1963 (1980).
P. Barberi, Bull. Inform. Sci. Technol. CEA,180, 55 (1973).
D. P. Chong, F. G. Herring, and Y. Takahata, J, Electr. Spectr. Relat. Phenom.13, 39 (1978).
A. V. Dudin, A. V. Baluev, and L. N. Gorokhov, Izv. Akad. Nauk SSSR, Ser. Khim., 1306 (1978).
A. V. Dudin, A. V. Baluev, and L. N. Gorokhov, Izv. Akad. Nauk SSSR, Ser. Khim., 2172 (1979).
K. O. Christe and C. I. Schack, Advances Inorg. Chem. and Radiochemistry, New York (1976), Vol. 18, p. 319.
E. R. Moelwyn-Hughes, Physical Chemistry [Russian translation], Izd. Inostr. Lit., Moscow (1962), Vol. 1, p. 452.
V. N. Kondrat'ev (editor), Handbook. Energy for the Breaking of Chemical Bonds. Ionization Potentials and Electron Affinity [in Russian], Nauka, Moscow (1974).
J. L. Franklin, J. Chem. Phys.,193, 725 (1976).
D. K. Bulgin, I. H. Dyke, N. Jonathan, and A. Morris, J. Chem. Soc. Faraday Trans., II, 456 (1979).
J. Berkowitz, P. A. Dehwer, and W. A. Chapka, J. Chem. Phys.,59, 925 (1973).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1084–1090, May, 1983.
The authors wish to express their gratitude to V. Ya. Rosolovskii and L. N. Gorokhov for participation in the discussion of the results.
Rights and permissions
About this article
Cite this article
Alekseev, V.I., Fedorova, L.I. & Baluev, A.V. Mass-spectrometric investigation of the thermochemical characteristics of perchloryl fluoride and its decomposition product—chlorosyl fluoride. Russ Chem Bull 32, 980–986 (1983). https://doi.org/10.1007/BF00956150
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00956150