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Protonated forms of vinyl ethers

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It has been shown by means of the semiempirical MINDO/2 method that in the addition of an isolated proton to methyl vinyl ether, it is possible to form species protonated through the 0 atom, in which the proton is not fixed by the 2p-unshared pair, but by a hybridized orbital close to sp2, lying in the Cβ-Cα-0 plane.

  2. 2.

    For the form protonated through the Cβ, we have established the formation of a structure that can be regarded as a complex of

    and H2.

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Literature cited

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    R. Kh. Zacheslavskaya, L. Ya. Rappoport, G. N. Petrov & B. A. Trofimov

  2. S. V. Lebedev All-Union Scientific-Research Institute of Synthetic Rubber, Leningrad

    R. Kh. Zacheslavskaya, L. Ya. Rappoport, G. N. Petrov & B. A. Trofimov

Authors
  1. R. Kh. Zacheslavskaya
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  2. L. Ya. Rappoport
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  3. G. N. Petrov
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  4. B. A. Trofimov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 982–986, May, 1983.

The authors wish to thank Yu. L. Frolov for discussion and advice.

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Zacheslavskaya, R.K., Rappoport, L.Y., Petrov, G.N. et al. Protonated forms of vinyl ethers. Russ Chem Bull 32, 886–889 (1983). https://doi.org/10.1007/BF00956132

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  • DOI: https://doi.org/10.1007/BF00956132

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