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Carbomagnesiation of several norbornene derivatives catalyzed by Cp2ZrCl2

  • U. M. Dzhemilev
  • O. S. Vostrikova
  • R. M. Sultanov
Brief Communications

Conclusions

  1. 1.

    Cp2ZrCl2 catalyzes the stereoselective cis-carbomagnesiation of norbornene and dicyclopentadiene by diethylmagnesium and ethylmagnesium bromide.

     
  2. 2.

    In the case of norbornadiene, the carbomagnesiation is accompanied by an intramolecular rearrangement leading to a substituted nortricyclene.

     

Keywords

Bromide Norbornene Norbornadiene Intramolecular Rearrangement Cp2ZrCl2 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • U. M. Dzhemilev
    • 1
  • O. S. Vostrikova
    • 1
  • R. M. Sultanov
    • 1
  1. 1.Institute of Chemistry, Bashkir BranchAcademy of Sciences of the USSRUfa

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