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EPR spectroscopic study of free-radical addition of mercaptans and polyhalomethanes to substituted alkenylcyclopropanes by spin trapping

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Using nitrosodurene as a spin trap, the addition of CCl3 and PhS radicals to substituted alkenylcyclopropanes was studied by EPR. The formation of spin adducts of cyclopropylcarbinyl and allylcarbinyl radicals with nitrosodurene was established.

  2. 2.

    The rate constant of the isomerization of cyclopropylcarbinyl to allylcarbinyl radicals was determined and it was shown that this rearrangement is quite rapid (isomerization constant 106–107 sec−1).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. M. Guliev, A. N. Leraeshev, R. G. Gasanov & O. M. Nefedov

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. M. Guliev, A. N. Leraeshev, R. G. Gasanov & O. M. Nefedov

  3. Institute of Chloroorganic Synthesis, Academy of Sciences of the Azerbaidzhan SSR, Sumgait

    A. M. Guliev, A. N. Leraeshev, R. G. Gasanov & O. M. Nefedov

Authors
  1. A. M. Guliev
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  2. A. N. Leraeshev
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  3. R. G. Gasanov
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  4. O. M. Nefedov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1341–1346, June, 1985.

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Guliev, A.M., Leraeshev, A.N., Gasanov, R.G. et al. EPR spectroscopic study of free-radical addition of mercaptans and polyhalomethanes to substituted alkenylcyclopropanes by spin trapping. Russ Chem Bull 34, 1227–1231 (1985). https://doi.org/10.1007/BF00956089

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  • DOI: https://doi.org/10.1007/BF00956089

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