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Synthesis and reactivity of cationic trimethyltetrafluorobenzobarrelene rhodium(I) complexes

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Summary

The preparation and properties of cationic rhodium(I) complexes of the types [Rh(Me3TFB)L2]PF6 (L=O. N. P, As or Sb-donor ligands, Me3TFB=trimethyltetrafluorobarrelene), [Rh(Me3TFB) (η6-arene)]PF6 (arene=C6Me6, C6H6Me3, C6H6 or C10H8) and [Rh(Me23TFB)(PPh3)L]PF6 (L=Me2CO or Me2SO) are described. Some complexes react with carbon monoxide at normal pressure with displacement of Me3TFB and formation of carbonyl derivatives. The arene-exchange behaviour for the new complex with naphthalene (C10H8) was examined in acetone solutions.

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Authors and Affiliations

  1. Facultad de Química, Pontificia Universidad Católica de Chile, Casilla 114-D, Santiago, Chile

    Mauricio Valderrama & Ricardo Ganz

  2. Departamento de Química, Universidad de Santiago, Santiago, Chile

    Renato Sariego

Authors
  1. Mauricio Valderrama
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  2. Ricardo Ganz
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  3. Renato Sariego
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Valderrama, M., Ganz, R. & Sariego, R. Synthesis and reactivity of cationic trimethyltetrafluorobenzobarrelene rhodium(I) complexes. Transition Met Chem 8, 160–162 (1983). https://doi.org/10.1007/BF00956025

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  • DOI: https://doi.org/10.1007/BF00956025

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