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Nitrosobenzene as a two-electron ligand in π-cyclopentadienyl and carbonyl complexes with group VI and VII transition metals

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Previously unknown derivatives of cymantrene and its rhenium analog [(η5-C5H5)M(CO)2(PhNO)] (M = Mn, Re) with nitrosobenzene as two-electron ligand, and also nitrosobenzene derivatives of group VI B metal carbonyl, were obtained and characterized.

  2. 2.

    All the compounds with PhNO ligands contain phenylnitrene and aniline ions in the mass spectra, the intensity of the latter being maximal.

  3. 3.

    In [W(CO)5(PhNO)], nitrosobenzene is extraordinarily easily reduced to the aniline ligand.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. N. Setkina, S. P. Dolgova, D. V. Zagorevskii, V. F. Sizoi & D. N. Kursanov

Authors
  1. V. N. Setkina
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  2. S. P. Dolgova
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  3. D. V. Zagorevskii
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  4. V. F. Sizoi
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  5. D. N. Kursanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1391–1395, June, 1982.

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Setkina, V.N., Dolgova, S.P., Zagorevskii, D.V. et al. Nitrosobenzene as a two-electron ligand in π-cyclopentadienyl and carbonyl complexes with group VI and VII transition metals. Russ Chem Bull 31, 1239–1243 (1982). https://doi.org/10.1007/BF00955988

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  • DOI: https://doi.org/10.1007/BF00955988

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