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Regioselectivity in the reaction of polyfluorinated β-diketones with hydroxyl-containing nucleophiles

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusion

Addition of water to nonsymmetrical β-diketones containing one fluoroalkyl substituent takes place at the

grouping of the enol form. Increasing the length of the fluoroalkyl substituent from HCF2 to n-C4H9 results in a reduction in the amount of the hydrated form.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Ural Scientific Center, Academy of Sciences of the USSR, Sverdlovsk

    K. I. Pashkevich, A. N. Fomin, V. I. Saloutin, D. V. Bazhenov & Yu. K. Grishin

  2. M. V. Lomonosov Moscow State University, USSR

    K. I. Pashkevich, A. N. Fomin, V. I. Saloutin, D. V. Bazhenov & Yu. K. Grishin

Authors
  1. K. I. Pashkevich
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  2. A. N. Fomin
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  3. V. I. Saloutin
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  4. D. V. Bazhenov
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  5. Yu. K. Grishin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1359–1367, June, 1982.

The authors thank Yu. A. Ustynyuk for discussions of the results.

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Pashkevich, K.I., Fomin, A.N., Saloutin, V.I. et al. Regioselectivity in the reaction of polyfluorinated β-diketones with hydroxyl-containing nucleophiles. Russ Chem Bull 31, 1210–1217 (1982). https://doi.org/10.1007/BF00955981

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  • DOI: https://doi.org/10.1007/BF00955981

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