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Some features of the synthesis of urethanes by the carbonylation of nitrobenzenes in alcoholic solution

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusion

  1. 1.

    The activating effect of VCl3 on PdCl2 has been established in the synthesis of carbamates by the carbonylation of nitrobenzenes in ethanol solution.

  2. 2.

    The principle features of the reaction have been established, and a generalized scheme for the reaction proposed.

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Literature cited

  1. B. K. Nefedov, The Synthesis of Organic Compounds from Carbon Monoxide [in Russian], Nauka, Moscow (1978).

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  4. O. N. Temkin, O. L. Kaliya, L. N. Zhir-Lebed', V. A. Golodov, L. G. Bruk, and N. G. Mekhryakova, in: Homogeneous Oxidation [in Russian], Nauka, Alma-Ata, Kaz. SSR,17, p. 3 (1978).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Manov-Yuvenskii, B. K. Nefedov & Kh. O. Khoshdurdyev

Authors
  1. V. I. Manov-Yuvenskii
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  2. B. K. Nefedov
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  3. Kh. O. Khoshdurdyev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1320–1322, June, 1982.

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Manov-Yuvenskii, V.I., Nefedov, B.K. & Khoshdurdyev, K.O. Some features of the synthesis of urethanes by the carbonylation of nitrobenzenes in alcoholic solution. Russ Chem Bull 31, 1176–1178 (1982). https://doi.org/10.1007/BF00955972

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  • DOI: https://doi.org/10.1007/BF00955972

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