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Structure of binuclear adducts of Cu(II) carbamates and phosphates with bases from ESR data

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusion

  1. 1.

    For adducts of copper(II) carbamate and phosphate complexes in solutions a binuclear structure of the half-open lantern type is realized in which the two Cu2+ ions are connected only By two bridge anions present in the cis position relative to one another. The parameters of the ESR spectra for this low-symmetry structure have been assigned by modeling the spectra on a computer.

  2. 2.

    The rhombic component of the fine structure in the ESR spectra has been interpreted on the basis of a model of dipole-dipole interactions for nonpunctate magnetic dipoles.

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Literature cited

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    E. G. Boguslavskii & A. A. Shklyaev

  2. Institute of Chemistry and Chemical Technology, Siberian Branch, Academy of Sciences of the USSR, Krasnoyarsk

    E. G. Boguslavskii & A. A. Shklyaev

Authors
  1. E. G. Boguslavskii
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  2. A. A. Shklyaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1302–1306, 1982.

The authors express their sincere thanks to A. P. Gerasev for assistance in setting up the program for calculating the spectrum.

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Boguslavskii, E.G., Shklyaev, A.A. Structure of binuclear adducts of Cu(II) carbamates and phosphates with bases from ESR data. Russ Chem Bull 31, 1159–1163 (1982). https://doi.org/10.1007/BF00955969

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  • DOI: https://doi.org/10.1007/BF00955969

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