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Stereochemical features of the paramagnetic complex formed by the reaction of 3,6-di-tert-butyl-o-benzoquinone with tetrachlorostannane

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusion

  1. 1.

    In 3,6-di-tert-butyl-2-hydroxytrichlorostannylphenoxyl, the SnCl3 group experiences hindered rotation the energy barrier of which shows a bond of the tin atom with both oxygen atoms of the free-radical ligand.

  2. 2.

    A transformation of the pentacoordination structure of the complex (I) into an octahedral structure on the coordination of electron-donating molecules with the tin atom has been detected.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. I. Prokof'ev, Z. K. Kasymbekova, N. N. Budnov, S. P. Solodovnikov & M. I. Kabachnik

Authors
  1. A. I. Prokof'ev
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  2. Z. K. Kasymbekova
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  3. N. N. Budnov
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  4. S. P. Solodovnikov
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  5. M. I. Kabachnik
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp, 1275–1282, 1982.

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Prokof'ev, A.I., Kasymbekova, Z.K., Budnov, N.N. et al. Stereochemical features of the paramagnetic complex formed by the reaction of 3,6-di-tert-butyl-o-benzoquinone with tetrachlorostannane. Russ Chem Bull 31, 1136–1142 (1982). https://doi.org/10.1007/BF00955964

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  • DOI: https://doi.org/10.1007/BF00955964

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