Summary
Acrylonitrile was polymerized by an insertion process on being added to solutions containing the adduct of the reaction of tetrakis(dimethylamino) titanium (T4) and azobisisobutyronitrile (AIBN). The obtained azo-linked polyacrylonitrile has appropriate initiating functionality for a subsequent vinyl polymerization.
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Yagci, Y., Menceloglu, Y.Z., Baysal, B.M. et al. Acrytonitrile block copolymers. Polymer Bulletin 21, 259–263 (1989). https://doi.org/10.1007/BF00955916
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DOI: https://doi.org/10.1007/BF00955916