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Reaction of 2-acetyl-5-methyl-1, 2, 3-diazaphosphole with diazoacetic ester

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Independent of the nature of the solvent, the reaction of 2-acetyl-5-methyl-1,2,3-diazaphosphole with diazoacetic ester proceeds without the evolution of nitrogen to give Δ2-phosphapyrazoline derivatives. The latter in CH2Cl2, CH3CN, or alcohols are isomerized to compounds with two NH groups.

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Literature cited

  1. B. A. Arbuzov, É. N. Dianova, and Yu. Yu. Samitov, Dokl. Akad. Nauk SSSR,244, 1117 (1979).

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Authors and Affiliations

  1. A. M. Butlerov Chemical Institute of the V. I. Ul'yanov-Lenin Kazan State University, USSR

    B. A. Arbuzov, A. F. Lisin & É. N. Dianova

Authors
  1. B. A. Arbuzov
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  2. A. F. Lisin
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  3. É. N. Dianova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2395–2397, October, 1983.

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Arbuzov, B.A., Lisin, A.F. & Dianova, É.N. Reaction of 2-acetyl-5-methyl-1, 2, 3-diazaphosphole with diazoacetic ester. Russ Chem Bull 32, 2158–2160 (1983). https://doi.org/10.1007/BF00955796

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  • DOI: https://doi.org/10.1007/BF00955796

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