Alkali-catalyzed hydration of stereoisomeric 3,4-epoxycaranes

  • É. Kh. Kazakova
  • L. N. Surkova
Brief Communications
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Conclusions

The alkali-catalyzed hydration of the stereoisomeric 3,4-epoxycaranes gives a mixture of the expected glycols, together with the skeletal rearrangement product in the case of the cis-epoxide.

Keywords

Hydration Glycol Rearrangement Product Skeletal Rearrangement 

Literature cited

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    É. Kh. Kazakova, L. N. Surkova, and S. V. Andreeva, Izv. Akad. Nauk SSSR, Ser. Khim., 1636 (1982).Google Scholar
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    H. Schmidt, P. Richter, and M. Mulstädt, Chem. Ber.,96, 2636 (1963).Google Scholar
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    R. R. D'yakonova, A. A. Musina, R. G. Gainullina, and A. G. Chernov, Izv. Akad. Nauk SSSR, Ser. Khim., 1327 (1982).Google Scholar
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    B. A. Arbuzov and Z. G. Isaeva, Usp. Khim.,8, 1339 (1976).Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • É. Kh. Kazakova
    • 1
  • L. N. Surkova
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan BranchAcademy of Sciences of the USSRUSSR

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