Conclusions
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1.
The nature and structure of the substituent in arylsulfinic acids slightly influence the direction of their telomerization with butadiene, and in almost all experiments this leads to a mixture of butenyl and octadienyl sulfones.
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2.
Low-valence palladium complexes, modified by secondary amines, nitrobenzene, or 18-dibenzo-6-crown ether, are effective catalysts of the telomerization of aromatic sulfinic acids with butadiene.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2337–2346, October, 1983.
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Dzhemilev, U.M., Kunakova, R.V. & Gaisin, R.L. Synthesis of aromatic and heteroaromatic unsaturated sulfones using palladium complex catalysts. Russ Chem Bull 32, 2107–2114 (1983). https://doi.org/10.1007/BF00955782
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DOI: https://doi.org/10.1007/BF00955782