Conclusions
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1.
A high catalytic activity has been shown for a number of indigenous high-silica zeolites: TsVK-I, TsVK-III, TsVM, and a boron-containing silicate in the total conversion of methanol to hydrocarbons. The most effective catalysts are the boron-containing silicate and NTsVM modified by Group VIII metals.
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2.
Like methanol, a number of other oxygen-containing compounds (ethers, ketones) as well as ethylene are converted into aliphatic and aromatic hydrocarbons in the presence of high-silica zeolites to form reaction products of similar qualitative composition.
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3.
It is postulated that under the conditions studied the compounds investigated are converted into the cited hydrocarbons according to a single scheme.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.10, pp. 2311–2316, October, 1983.
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Bragin, O.V., Vasina, T.V., Preobrazhenskii, A.V. et al. Conversion of methanol and some other oxygen-containing compounds into aromatic hydrocarbons and components of high-octane fuel. Russ Chem Bull 32, 2086–2090 (1983). https://doi.org/10.1007/BF00955777
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DOI: https://doi.org/10.1007/BF00955777