Conclusions
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1.
An equation has been proposed for the calculation of molar Cotton-Mouton constants from solution data.
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2.
The magnetic susceptibility ellipsoids of C-Cl and C-Br bonds and of the C-CH3 groups in a number of substituted benzenes have been found.
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Literature cited
P. W. Selwood, Magnetochemistry, Interscience Publ., New York (1956).
W. Haberditzl, Magnetochemie, Akademische Verlag, Berlin (1968).
W. H. Flygare, Chem. Rev.,74, 653 (1974).
M. A. Lasheen, Phil. Trans. Roy. Soc. London, A,256, 357 (1964).
J. Homer and D. Callaghan, J. Chem. Soc., A, 439 (1968).
A. D. Buckingham, W. H. Prichard, and D. H. Whiffen, Trans. Faraday Soc.,63, 1057 (1967).
R. J. W. Le Fevre, P. H. Williams, and J. M. Eckert, Austral. J. Chem.,18, 1133 (1965).
A. D. Buckingham and J. A. Pople, Proc. Phys. Soc., B,69, 1133 (1956).
A. N. Vereshchagin, The Polarizability of Molecules [in Russian], Nauka, Moscow (1980).
R. J. W. Le Fevre and D. S. N. Murthy, Austral. J. Chem.,19, 179 (1966).
R. J. W. Le Fevre and D. S. N. Murthy, Austral. J. Chem.,19, 1315 (1966).
R. J. W. Le Fevre and D. S. N. Murthy, Austral. J. Chem.,19, 1321 (1966).
A. Weissberger and B. W. Rossiter (eds.), Physical Methods of Chemistry, Vol. 1, Part IV, Interscience Publishers, New York (1972), p. 561.
E. J. Burge and O. Snellmann, Phil. Mag.,40, 994 (1949).
M. R. Battaglia and G. L. D. Ritchie, J. Chem. Soc. Faraday Trans. 2,73, 209 (1977).
C. L. Cheng, D. S. N. Murthy, and G. L. D. Ritchie, Austral. J. Chem.,25, 1301 (1972).
V. I. Minkin, O. A. Osipov, and Yu. A. Zhdanov, Dipole Moments in Organic Chemistry [in Russian], Khimiya, Leningrad (1968).
Handbook of Chemistry, Vol. 1 [in Russian], Khimiya, Leningrad (1971).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2296–2301, October, 1983.
The authors express their thanks to B. A. Arbuzov for his constant attention to the work and invaluable remarks.
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Vul'fson, S.G., Nikolaev, V.F. & Vereshchagin, A.N. Cotton — Mouton constants and the anisotropy of the magnetic susceptibility of substituted benzenes. Russ Chem Bull 32, 2073–2078 (1983). https://doi.org/10.1007/BF00955774
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DOI: https://doi.org/10.1007/BF00955774