Conclusions
-
1.
It was determined by EPR that prolonged photolysis of Mo(CO)6 solutions in the presence of 3,5-di-tert-butyl-o-quinone and 3,6-di-tert-butyl-o-quinone form paramagnetic molybdenum complexes containing the oxymolybdate group as well as orthoquinone ligands.
-
2.
It is suggested that the oxygen in the oxymolybdate group is derived from the o-quinones.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
W. R. Harris, C. J. Carrano, and K. N. Raymond, J. Am. Chem. Soc.,101, 2213 (1979).
A. V. Lobanov, G. A. Abakumov, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR,235, 824 (1977).
C. G. Pierpont and R. M. Buchanan, Coord. Chem. Rev.,38, 45 (1981).
R. M. Buchanan and C. G. Pierpont, Inorg. Chem.,18, 1616 (1979).
C. G. Pierpont and H. H. Downs, J. Am. Chem. Soc.,97, 2123 (1975).
C. G. Pierpont and R. M. Buchanan, J. Am. Chem. Soc.,97, 6450 (1975).
D. Weir and J. K. S. Wan, J. Organomet. Chem.,220, 323 (1981).
M. Wrighton, Chem. Revs.,74, 406 (1974).
I. N. Marov and N. A. Kostromina, EPR and NMR in the Chemistry of Coordination Compounds [in Russian], Nauka, Moscow (1979), p. 45.
K. Sarbasov, S. P. Solodovnikov, B. L. Tumanskii, N. N. Bubnov, and A. I. Prokof'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 1509 (1982).
V. B. Vol'eva, I. A. Novikova, G. D. Ostapets-Sveshnikova, I. S. Belostotskaya, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 2416 (1980).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2236–2240, October, 1983.
Rights and permissions
About this article
Cite this article
Sarbasov, K., Tumanskii, B.L., Solodovnikov, S.P. et al. Photochemical reaction of molybdenum hexacarbonyl with o-quinones. Russ Chem Bull 32, 2018–2022 (1983). https://doi.org/10.1007/BF00955762
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00955762