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Effect of the viscosity of monomeric solutions on the rate constant of bimolecular chain breaking in radical polymerization of N,N-dialkyl-N,N-diallylammonium halides

  • D. A. Topchiev
  • G. T. Nazhmetdinova
  • A. I. Kartashevskii
  • A. V. Nechaeva
  • V. A. Kabanov
Physical Chemistry
  • 35 Downloads

Conclusions

The nonlinear increase in the initial rate of radical polymerization of N,N-dialkyl-N,N-diallylammonium halides in aqueous and methanol solutions as the starting concentration of the monomer increases is due to a decrease in the rate constant of bimolecular chain breaking with an increase in the viscosity of the starting solutions of the monomer.

Degradation transfer of chains to the monomer, characteristics of polymerization of allyl monomers, is absent in the reactions studied.

Keywords

Polymerization Viscosity Methanol Initial Rate Halide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • D. A. Topchiev
    • 1
  • G. T. Nazhmetdinova
    • 1
  • A. I. Kartashevskii
    • 1
  • A. V. Nechaeva
    • 1
  • V. A. Kabanov
    • 1
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow

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