Skip to main content
SpringerLink
Log in

Reactions of formation and decomposition of tetracyanocyclobutane derivatives of carbazole and phenothiazine

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

On investigating the kinetics of the reactions of formation and decomposition of tetracyanocyclobutane derivatives of carbazole and phenothiazine we determined the fundamental characteristics of the course of the side reaction of hydrolysis, polymerization, and dehydro cyanation accompanying the cycloaddition reaction. It seems that in polar media hydrolysis and polymerization precede the steps of formation of donor-acceptor complexes, dehydrocyanation, and formation of zwitterions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. J. K. Williams, D. W. Wiley, and B. C. McKusik, J. Am. Chem. Soc.,84, 2210 (1962).

    Google Scholar 

  2. C. E. H. Bawn, A. Ledwith, M. Sambhi, Polymer,12, 209 (1971).

    Google Scholar 

  3. A. G. Gorshkov, V. K. Turchaninov, G. N. Kurov, and G. G. Skvortsova, Zh. Org. Khim.,15, 767 (1979).

    Google Scholar 

  4. N. I. Shergina, G. G. Skvortsova, G. N. Kurov, and T. D. Taryashinova, Zh. Prikl. Spektrosk.,13, 845 (1970).

    Google Scholar 

  5. N. Nakahara, Y. Tsuda, M. Sasaki, and O. Osugi, Chem. Lett., 731 (1976).

  6. N. S. Isaacs, J. Chem. Soc. B, 1053 (1966).

    Google Scholar 

  7. W. Y. Middleton, E. Z. Zittle, J. C. Coffman, and V. A. Englehardt, J. Am. Chem. Soc.,80, 2795 (1958).

    Google Scholar 

  8. G. N. Kurov, L. I. Svyatkina, G. G. Skvortsova, and I. P. Naumova, Izv. Akad. Nauk SSSR, Ser. Khim., 2235 (1982).

  9. A. Gordon and R. Ford, The Chemist's Companion. A Handbook of Practical Data, Techniques and References, Wiley, New York (1972).

    Google Scholar 

  10. I. A. Koppel' and A. I. Payu, Reaction Capability of Organic Compounds,11, (1) (1974).

  11. T. Nakamura, M. Soma, T. Onishi, and K. Tamura, Makromol. Chem.,135, 241 (1970).

    Google Scholar 

  12. G. N. Kurov, L. I. Trotsenko, L. L. Gaintseva, E. N. Suslova, V. K. Turchaninov, and G. G. Skvortsova, Vysokomol. Soedin.,66, 216 (1979).

    Google Scholar 

  13. A. G. Gorshkov, V. K. Turchaninov, L. I. Svyatkina, G. N. Kurov, and G. G. Skvortsova Vysokomol, Soedin.,24, 1135 (1982).

    Google Scholar 

  14. S. I. Peredereeva, Dissertation, Moscow (1973).

Download references

Author information

Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    G. N. Kurov, L. I. Svyatkina & E. G. Pal'chuk

Authors
  1. G. N. Kurov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. I. Svyatkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. G. Pal'chuk
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2227–2231, October, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kurov, G.N., Svyatkina, L.I. & Pal'chuk, E.G. Reactions of formation and decomposition of tetracyanocyclobutane derivatives of carbazole and phenothiazine. Russ Chem Bull 32, 2009–2013 (1983). https://doi.org/10.1007/BF00955760

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00955760

Keywords

Search

Navigation